I think this is getting a little more complicated than it needs to be. What if you create your primary alert for "if server is down send email through primary mail" and leave that one alone, but setup another alert that is "if primary mail server is down send mail through secondary mail". Why suppress the other alert because that mail server is down? Is there another motive/objective than just to get you an alert through another mail server when the primary is not available? (I always try to make things a simple as possible - less troubleshooting).
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